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Narcissistic, Integrative, and Kinetic Self-Sorting within a System of Coordination Cages

Felix J. Rizzuto, Jonathan R. Nitschke

2020Journal of the American Chemical Society74 citationsDOIOpen Access PDF

Abstract

template ions. The underlying rules dictating the organization of assemblies into specific shapes are deciphered, explaining the formation of only three discrete entities when five could form in principle.

Topics & Concepts

ChemistryTetrahedronOctahedronCube (algebra)PolyhedronSortingChemical physicsComplex systemOrientation (vector space)Self-assemblySymmetry (geometry)Structural complexityCrystallographyTopology (electrical circuits)Biological systemCombinatoricsComputer scienceCrystal structureAlgorithmGeometryMathematicsArtificial intelligenceBiologyOrganic chemistrySupramolecular Chemistry and ComplexesCrystallography and molecular interactionsMolecular Sensors and Ion Detection
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