Detection of NH3 impurities in H2 environment exploiting quartz-enhanced photoacoustic spectroscopy with an optimized spectrophone
Chaofan Feng, Ruyue Cui, Giansergio Menduni, Andrea Zifarelli, Pietro Patimisco, Angelo Sampaolo, Vincenzo Spagnolo, Lei Dong, Hongpeng Wu
Abstract
We report on a quartz-enhanced photoacoustic spectroscopy (QEPAS) sensor for ammonia impurities detection in hydrogen. A quantum cascade laser with a central emission wavelength of 9.062 μm was used to excite the NH 3 absorption line at 1103.44 cm −1 , with a linestrength of 1.51ꞏ10 −19 cm/molecule. Compared to detecting contaminants in ambient air, the distinct properties of hydrogen required the design of a dedicated QEPAS spectrophone optimized for operation in hydrogen-based mixtures. The custom-made spectrophone was composed by a QTF excited at the first overtone mode at 44 kHz, acoustically coupled with an easy-to-align, dual-tube amplification system. The custom-made spectrophone was implemented in a QEPAS sensor, achieving a minimum detection limit of 95 ppb with a lock-in integration time of 0.1 s. Furthermore, the Allan-Werle deviation analysis returned a detection limit as low as 1.5 ppb when for an integration time of 30 s. • QEPAS sensor for ammonia detection in hydrogen-based mixtures. • Custom design spectrophone optimized for hydrogen environments. • Spectrophone with QTF operating at the first overtone mode at 44 kHz and dual-tube amplification system. • Minimum detection limit: 95 ppb with 0.1-s integration time. • Demonstrated QEPAS as a viable technology for in situ hydrogen purity monitoring, aligning with ISO 14687:2019 standards.