Aluminum-Containing Heterobimetallic Complexes as Versatile Platforms for Homogeneous Catalysis
Roushan Prakash Singh, Soumen Sinhababu, Neal P. Mankad
Abstract
Within the broader area of heterobimetallic catalysis, Al/M compounds (M = any metal) are promising for the design and execution of catalytic manifolds. This Perspective reviews recent advances in Al/M heterobimetallic catalysis, focusing on their catalytic applications. Topics include polymerization, epoxide activation and carbonylation, C–H functionalization, and other important catalytic transformations mediated by Al/M catalysts. In each case, the mechanistic role of the aluminum site is highlighted. A broad range of Al-containing metalloligands and Al/M combinations is included to construct this comprehensive perspective.
Topics & Concepts
CatalysisEpoxideHomogeneousCarbonylationHomogeneous catalysisCombinatorial chemistryChemistrySurface modificationNanotechnologyMaterials scienceOrganic chemistryCarbon monoxidePhysicsPhysical chemistryThermodynamicsCarbon dioxide utilization in catalysisOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and Catalysis