Engineering Biomass Feedstock Cyrene to Value-Added Compounds by Enaminone Platform Construction
Lizhu Huang, Yunyun Liu, Jie‐Ping Wan
Abstract
The enamination of Cyrene in the ketone α-site leading to the enamino Cyrene (EC) has been developed.The practical preparation of EC as a platform synthon opens broad space of chemical transformation for Cyrene biomass feedstock in the synthesis of diverse value-added chemicals.In the present work, the transformation of the EC for the synthesis of many different chiral organic derivatives, including NH-/N,N-disubstituted ECs, the cyanoalkenyl-and vinyl phosphine oxide-elaborated Cyrene, Cyrene fused furan, and 2,2-difluorodihydrofuran fused Cyrene, has been realized.
Topics & Concepts
ChemistryRaw materialBiomass (ecology)Pulp and paper industryValue (mathematics)Value addedOrganic chemistryAgronomyEngineeringMathematicsEconomicsMacroeconomicsStatisticsBiologyCatalysis for Biomass ConversionChemistry and Chemical EngineeringCatalysis and Hydrodesulfurization Studies