Binuclear Metal-Based Covalent Organic Framework Mimicking Metallohydrolases for Direct Photoreforming of PET Plastic
Minghao Qin, Pei Huang, Mi Zhang, Cheng Xiao, Jiayi Chen, Yida Zhou, Meng Lu, Jiyang Li, Ya‐Qian Lan
Abstract
, with ∼100% conversion toward PET photoreforming. The mechanism of PET depolymerization and intermediates promoting hydrogen evolution was studied through density functional theory calculations. This work provides a new idea and a sustainable route for the rational design and development of function-integrated materials for upgrading plastic waste into value-added chemicals.
Topics & Concepts
ChemistryDepolymerizationCatalysisEthyleneEthylene glycolFormic acidCovalent bondHydrogenOrganic chemistryCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMicroplastics and Plastic Pollution