Probing the ionic structure of FLiNaK–ZrF<sub>4</sub> salt mixtures by solid-state NMR
Rongshan Lan, Yiyang Liu, Ling Han, Jing Yang, Huiqin Yin, Min Ge, Xiaobin Fu, Hongtao Liu, Yuan Qian
Abstract
The evolution of the [Zr<sub>x</sub>F<sub>y</sub>]<sup>4x−y</sup> ionic structures in FLiNaK–ZrF<sub>4</sub> salt mixtures was elucidated through solid-state NMR techniques when the melt salts were being solidified.
Topics & Concepts
Ionic bondingSalt (chemistry)Solid-state nuclear magnetic resonanceSolid-stateMaterials scienceChemistryInorganic chemistryPhysical chemistryIonNuclear magnetic resonanceOrganic chemistryPhysicsAdvanced NMR Techniques and ApplicationsInorganic Fluorides and Related CompoundsAdvanced Battery Materials and Technologies