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Excellent Wavelength Selectivity of p-AlGaN/n-Ga<sub>2</sub>O<sub>3</sub> Solar-Blind UVC PD

Xiyao He, Ruoting Sun, Xiangyu Xu, Hansong Geng, Shengli Qi, Kelvin H. L. Zhang, Hao Long

2024ACS Applied Materials & Interfaces17 citationsDOI

Abstract

Due to the advantages of ultrawide bandgap, chemical stability, self-powered, and low cost, gallium oxide (Ga 2 O 3 ) based photodetectors (PDs) are considered as one of the most promising solar-blind ultraviolet PDs, having garnered significant attention in fields such as missile warning and flame arc detection. High selective ratios and excellent responsivity are important to reduce the false alarm rate in solar-blind detection. However, due to the lack of p-type Ga 2 O 3, existing Ga 2 O 3 -based PN PDs utilized heterostructures with narrower bandgap p-type semiconductors (e.g., p-GaN, p-SiC, etc.), inducing poor selective ratios with visible light and ultraviolet-A/B (UVA/B). Therefore, a high Al content AlGaN was used in this study to form a p-AlGaN/n-Ga 2 O 3 solar-blind ultraviolet-C (UVC) PD. Since the bandgap of p-AlGaN aligned with the UVC region, the device exhibited exceptionally high selective ratios with R 247nm /R 360nm = 3.71 × 10 5 and R 247nm /R 300nm = 1.47 × 10 5 at 0 V, which surpassed the reported Ga 2 O 3 -based PN PDs. The formation of the type-II heterojunction facilitated the effective separation and transport of photogenerated carriers, resulting in high responsivity (0.36 A/W) under zero bias. Overall, the high selective ratios and high responsivity of the p-AlGaN/n-Ga 2 O 3 PD in this paper provided a reliable pathway for self-powered solar-blind PDs with a low false alarm rate.

Topics & Concepts

Materials scienceWavelengthSelectivityOptoelectronicsChemistryBiochemistryCatalysisGa2O3 and related materialsZnO doping and propertiesGaN-based semiconductor devices and materials