The competitive role of C–H⋯X (X = F, O) and π–π interactions in contributing to the degree of charge transfer in organic cocrystals: a case study of heteroatom-free donors with <i>p</i>-fluoranil (FA)
Jiaoyang Gao, Jinjia Guo, Yi Chen, Shunlan Deng, Qidong Lu, Yuxin Ren, Xiaoming Wang, Haibo Fan, Feng Teng, Xuexia He, Hui Jiang, Peng Hu
Abstract
Four binary organic charge transfer cocrystals were grown by the slow cooling method. The competitive role of C–H⋯X (X = F, O) and π–π interactions in contributing to the degree of charge transfer in the cocrystals was investigated.
Topics & Concepts
HeteroatomCharge (physics)Degree (music)CrystallographyMaterials scienceChemistryOrganic chemistryPhysicsAcousticsRing (chemistry)Quantum mechanicsOrganic and Molecular Conductors ResearchCrystallography and molecular interactionsNonlinear Optical Materials Research