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Suppression of Dendrites by a Self-Healing Elastic Interface in a Sodium Metal Battery

Jianwen Wang, Meiyang Hu, Yingying Zhu, Mengyang Cao, Rashid Khan, Xianwen Wang, Lu Huang, Yingpeng Wu

2023ACS Applied Materials & Interfaces11 citationsDOI

Abstract

The safety issues caused by sodium dendrites limit the widespread application of sodium metal batteries. Herein, a self-healing polymer electrolyte (SPE) is prepared by immersing the self-healing polymer in a liquid electrolyte. Benefiting from the self-healing properties, elastic interface, and dense nonporous structure of the SPE, the fabricated NaK|MC SPE|NaK symmetric battery presents a long battery life (∼590 h) and low polarization voltage (192 mV). Moreover, the PTCDA|MC SPE|NaK full cell also delivers stable long cycles and outstanding rate performance.

Topics & Concepts

Materials scienceElectrolyteBattery (electricity)PolymerPolarization (electrochemistry)SodiumSelf-healingChemical engineeringPorosityMetalComposite materialElectrodeMetallurgyPower (physics)ChemistryPhysical chemistryAlternative medicineMedicineEngineeringQuantum mechanicsPathologyPhysicsAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsAdvanced battery technologies research
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