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Reliability Improvement from La<sub>2</sub>O<sub>3</sub> Interfaces in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub>‐Based Ferroelectric Capacitors

Furqan Mehmood, Ruben Alcala, Pramoda Vishnumurthy, Bohan Xu, Ridham Sachdeva, Thomas Mikolajick, Uwe Schroeder

2023Advanced Materials Interfaces35 citationsDOIOpen Access PDF

Abstract

Abstract Further optimization of a typically reported ferroelectric capacitor comprised of a Hf 0.5 Zr 0.5 O 2 ferroelectric thin film with TiN electrodes is explored by introducing an additional non‐ferroelectric La 2 O 3 interfacial layer evaluated at different positions in the capacitor stack. The role of the interface to the ferroelectric layer is investigated and discussed, with the main focus directed toward the reliability of the device for non‐volatile memory applications. With this investigation, different degradation mechanisms determining electric field cycling and polarization retention are observed, and it is concluded that modifying the bottom interface between the electrode and the ferroelectric layer has the best potential to provide a benefit in device performance.

Topics & Concepts

FerroelectricityMaterials scienceCapacitorElectrodePolarization (electrochemistry)TinFerroelectric capacitorOptoelectronicsStack (abstract data type)Layer (electronics)Reliability (semiconductor)Degradation (telecommunications)Non-volatile memoryDielectricNanotechnologyElectronic engineeringVoltageElectrical engineeringComputer scienceMetallurgyPhysical chemistryProgramming languageEngineeringChemistryPower (physics)PhysicsQuantum mechanicsFerroelectric and Negative Capacitance DevicesSemiconductor materials and devicesAdvanced Memory and Neural Computing