Visible-Light-Induced Decarboxylation of Dioxazolones to Phosphinimidic Amides and Ureas
Jie Pan, Hao‐Cong Li, Kai Sun, Shi Tang, Bing Yu
Abstract
A visible-light-induced external catalyst-free decarboxylation of dioxazolones was realized for the bond formation of N=P and N-C bonds to access phosphinimidic amides and ureas. Various phosphinimidic amides and ureas (47 examples) were synthesized with high yields (up to 98%) by this practical strategy in the presence of the system's ppm Fe.
Topics & Concepts
DecarboxylationCatalysisChemistryVisible spectrumPhotochemistryCombinatorial chemistryOrganic chemistryMaterials scienceOptoelectronicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods