Mechanistic and structural characterization of an iridium-containing cytochrome reveals kinetically relevant cofactor dynamics
Brandon J. Bloomer, Sean N. Natoli, Marc Garcia‐Borràs, J.H. Pereira, Derek B. Hu, Paul D. Adams, K. N. Houk, Douglas S. Clark, John F. Hartwig
Topics & Concepts
CofactorChemistryCyclopropanationIridiumStereochemistryReactivity (psychology)Active siteBiocatalysisCombinatorial chemistryCatalysisReaction mechanismEnzymeOrganic chemistryAlternative medicinePathologyMedicineCyclopropane Reaction MechanismsMetal-Catalyzed Oxygenation MechanismsEnzyme Catalysis and Immobilization