Design of castor oil‐based polyurethane thermal conductive structural adhesive for new energy batteries
Ao Ding, Guang Liu, Pingfan Xu, Yixin Wang, Yuying Zheng, Yaofa Luo, Zhang Li, Peikun Zhang, Ai‐Zheng Chen, Yuan Liu, Chao He
Abstract
Abstract A thermal conductive structural adhesive (TCSA) plays a crucial role in battery performance and safety. TCSA made of polyurethane (PU) has not only a good thermal conductivity but also good mechanical strength and substrate bonding strength. However, it has to be cost‐effective and easy to be prepared. This work aims to synthesize a series of castor oil‐based PU TCSAs with different amounts of thermal conductive powder using commercially available castor oil polyols, isocyanates, Al 2 O 3 , and additives. The shear strength of the TCSA containing 88% thermally conductivity powder reached 5.6 MPa, which was similar to that without the thermal conductivity fillers, but its toughness significantly decreased. Its thermal conductivity was as high as 1.8 W/mK, and it was thermally stable below 270°C.