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RETRACTED: Synthesis of Yttrium Superhydride Superconductor with a Transition Temperature up to 262 K by Catalytic Hydrogenation at High Pressures

Elliot Snider, Nathan Dasenbrock‐Gammon, Raymond McBride, Xiaoyu Wang, Noah Meyers, Keith V. Lawler, Eva Zurek, Ashkan Salamat, Ranga Dias

2021Physical Review Letters268 citationsDOIOpen Access PDF

Abstract

The recent observation of room-temperature superconductivity will undoubtedly lead to a surge in the discovery of new, dense, hydrogen-rich materials. The rare earth metal superhydrides are predicted to have very high-T_{c} superconductivity that is tunable with changes in stoichiometry or doping. Here we report the synthesis of an yttrium superhydride that exhibits superconductivity at a critical temperature of 262 K at 182±8 GPa. A palladium thin film assists the synthesis by protecting the sputtered yttrium from oxidation and promoting subsequent hydrogenation. Phonon-mediated superconductivity is established by the observation of zero resistance, an isotope effect and the reduction of T_{c} under an external magnetic field. The upper critical magnetic field is 103 T at zero temperature.

Topics & Concepts

YttriumSuperconductivityRaman spectroscopyRoom-temperature superconductorMaterials scienceCritical fieldTransition temperatureHigh-temperature superconductivityCondensed matter physicsPhysicsMetallurgyOxideOpticsHigh-pressure geophysics and materialsSuperconductivity in MgB2 and AlloysHydrogen Storage and Materials