Thiol-free arene C–H thioesterification enabled by a photoactive electron donor–acceptor complex
Yanqiu Jiang, Ang Gao, Ming‐Chen Fu
Abstract
the interrupted Pummerer reaction with an electron donor-acceptor complex strategy. The method enables late-stage modification of complex bioactive molecules, and operates effectively under natural sunlight, highlighting its potential synthetic value.
Topics & Concepts
ThiolChemistryElectron acceptorAcceptorElectron donorPhotochemistryOrganic chemistryCatalysisPhysicsCondensed matter physicsSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsSynthesis and Catalytic Reactions