Metal–Organic Framework (MOF)-Derived Catalyst for Oxygen Reduction Reaction (ORR) Applications in Fuel Cell Systems: A Review of Current Advancements and Perspectives
Karmegam Dhanabalan, Muthukumar Perumalsamy, Ganesan Sriram, Nagaraj Murugan, Shalu, Sadhasivam Thangarasu, Tae Hwan Oh
Abstract
High-porosity, crystalline, and surface-area-rich metal–organic frameworks (MOFs) may be employed in electrochemical energy applications for active catalysis. MOFs have recently been modified using secondary building blocks, open metal sites with large pore diameters, and functional ligands for electronic conductivity. They have the potential for excellent performance in fuel cell applications, and they have several possibilities to enhance the fundamental characteristics of mass and electron transportation. MOFs may be combined with other materials, such as solitary metal nanoparticles and carbon and nitrogen composites, to increase their catalytic efficacy, especially in oxygen reduction reaction (ORR). As a result, this study focuses on MOF derivatives for ORR applications, including porous carbon MOF, single metal MOF-derived composites, metal oxides, and metal phosphides. An efficient MOF electrocatalyst platform for ORR applications is presented, along with its prospects. These initiatives promote promising MOF electrocatalysts for enhancing fuel cell efficiency and pique curiosity for possible growth in subsequent research.