Photoredox-catalyzed stereo- and regioselective vicinal fluorosulfonyl-borylation of unsaturated hydrocarbons
Heyin Li, Mengjun Huang, Zhenlei Zou, Zhen Wang, Yifan Li, Chao Sun, Wangzhe Chen, Yi Pan, Weigang Zhang, Yi Wang
Abstract
the cleavage of the C-B and S(vi)-F bonds, including halogenation, Suzuki coupling, hydrogenation, and the SuFEX click reaction, which demonstrated the great potential of the VFSB moieties for use in skeleton linkage and drug modification.
Topics & Concepts
VicinalRegioselectivityBorylationChemistryCatalysisCombinatorial chemistryPhotochemistryOrganic chemistryAlkylArylFluorine in Organic ChemistrySulfur-Based Synthesis TechniquesRadical Photochemical Reactions