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Controlling the crystal structure of precisely spaced polyethylene-like polyphosphoesters

Tobias Haider, Oksana Suraeva, Miriam L. O’Duill, Julian Mars, Markus Mezger, Ingo Lieberwirth, Frederik R. Wurm

2020Polymer Chemistry23 citationsDOIOpen Access PDF

Abstract

We report the synthesis and crystallization behavior of polyethylene-like polyphosphates with a precise spacing of 20, 30, and 40 methylene groups between each phosphate group, which determined the crystal structure, lamellar, and crystal thickness.

Topics & Concepts

PolyethyleneLamellar structureCrystallizationCrystal (programming language)Crystal structureCrystallographyMaterials scienceGroup (periodic table)ChemistryComposite materialOrganic chemistryComputer scienceProgramming languagebiodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry Methods