Modulated synthesis and isoreticular expansion of Th-MOFs with record high pore volume and surface area for iodine adsorption
Zi‐Jian Li, Yu Ju, Bowen Yu, Xiaoling Wu, Huangjie Lu, Yongxin Li, Jing Zhou, Xiaofeng Guo, Zhi‐Hui Zhang, Jian Lin, Jian‐Qiang Wang, Shuao Wang
Abstract
Modulated synthesis and isoreticular expansion of Th-MOFs enable the stepwise construction of hierarchical complexes in which porosity and functionality can be fine-tuned, affording new Th-MOFs with a record high void space (74.0%), the largest surface area (3396.5 m2 g-1) among thorium materials, and excellent adsorption capacities toward radioactive iodine.
Topics & Concepts
AdsorptionIodineVolume (thermodynamics)Volume expansionChemical engineeringChemistryNanotechnologyMaterials sciencePhysical chemistryOrganic chemistryThermodynamicsMedicinePhysicsInternal medicineEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsRadioactive element chemistry and processingCovalent Organic Framework Applications