Ti-MOF single-crystals featuring an intracrystal macro–microporous hierarchy for catalytic oxidative desulfurization
Yu Shen, Xiao Yu, Zhan Liu, Jia-Min Lyu, Yilong Wang, Zhi‐Yi Hu, Yu Li, Minghui Sun, Lihua Chen, Bao‐Lian Su
Abstract
For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro-microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100-1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.
Topics & Concepts
Microporous materialMaterials scienceFlue-gas desulfurizationChemical engineeringHierarchyMacroporeTemplatePolymerCoordination polymerMoleculeCatalysisMetal-organic frameworkMacroNanotechnologyChemistryOrganic chemistryComputer scienceMesoporous materialComposite materialEngineeringMarket economyAdsorptionEconomicsProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications