A Mn(<scp>ii</scp>)–MOF with inherent missing metal-ion defects based on an imidazole-tetrazole tripodal ligand and its application in supercapacitors
Jun Wang, Shu‐Qi Deng, Tingting Zhao, Sheng‐Run Zheng, Song‐Liang Cai, Jun Fan, Wei‐Guang Zhang
Abstract
A metal-organic framework (MOF), namely SCNU-Z3, based on an imidazole-tetrazole tripodal ligand and Mn(ii), has been constructed. It exhibits a porous 3D framework composed of truncated octahedron cage subunits. Unexpected ligand-induced missing metal-ion defects were observed in the framework. In addition, the application of SCNU-Z3 in a supercapacitor was performed.
Topics & Concepts
TetrazoleImidazoleLigand (biochemistry)SupercapacitorMetalIonChemistryMaterials scienceInorganic chemistryStereochemistryOrganic chemistryElectrochemistryReceptorPhysical chemistryElectrodeBiochemistrySupercapacitor Materials and FabricationMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase Materials