Symmetry-breaking phase transitions, dielectric and magnetic properties of pyrrolidinium-tetrahalidocobaltates
Martyna Ksiądzyna, Vasyl Kinzhybalo, Alina Bieńko, W. Medycki, R. Jakubas, Cyril Rajnák, Roman Boča, Andrew Ozarowski, Mykhaylo Ozerov, Anna Piecha‐Bisiorek
Abstract
We report the physicochemical analysis of Co-based pyrrolidinium analogues: (C 4 H 10 N) 2 CoCl 4 and (C 4 H 10 N) 2 CoBr 4 . The results confirm that introducing mobile organic cations into an inorganic network might construct compounds with multiple properties.
Topics & Concepts
DielectricSymmetry (geometry)Phase (matter)Phase transitionSymmetry breakingMaterials scienceChemistryCondensed matter physicsPhysicsOrganic chemistryMathematicsQuantum mechanicsOptoelectronicsGeometryMagnetism in coordination complexesCrystal Structures and PropertiesSolid-state spectroscopy and crystallography