Stabilizing an exotic dianionic tetrazine bridge in a Ln <sub>2</sub> metallocene
Niki Mavragani, Alexandros A. Kitos, Akseli Mansikkamäki, Muralee Murugesu
Abstract
The first structurally and physically characterized complexes bearing the dianion radical of an s -tetrazine are presented and highlight the extraordinary ability of tetrazines to store more than one electron within their six-membered ring.
Topics & Concepts
MetalloceneTetrazineBridge (graph theory)ChemistryMaterials scienceOrganic chemistryPolymerizationMedicineInternal medicinePolymerMolecular Junctions and NanostructuresInorganic Chemistry and MaterialsGraphene research and applications