Intramolecular rearrangements guided by adaptive coordination-driven reactions toward highly luminescent polynuclear Cu(<scp>i</scp>) assemblies
Mehdi El Sayed Moussa, Ali Moustafa Khalil, Sloane Evariste, Hok‐Lai Wong, V. Delmas, Boris Le Guennic, Guillaume Calvez, Karine Costuas, Vivian Wing‐Wah Yam, Christophe Lescop
Abstract
Highly luminescent solid-state Cu<sub>6</sub>, Au<sub>2</sub>Cu<sub>10</sub> and Pt<sub>4</sub>Cu<sub>11</sub> derivatives are obtained in one step reaction thanks to adaptive coordination-driven supramolecular chemistry using pre-assembled flexible Cu(<sc>i</sc>) precursors.
Topics & Concepts
LuminescenceIntramolecular forceSupramolecular chemistryCoordination complexSolid-stateChemistryCrystallographyNanotechnologyMaterials sciencePhysical chemistryStereochemistryCrystal structureOrganic chemistryMetalOptoelectronicsMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMagnetism in coordination complexes