Hydroxyl radical-dominated selective oxidation of ethylbenzene over a photoactive polyoxometalate-based metal–organic framework
Jiachen Jiao, Ting Zhang, Jiangbo Xu, Kaixin Guo, Jie Li, Qiuxia Han
Abstract
A new photoactive POMOF with a stable structure, suitable band gap and good photoelectric properties was assembled. It exhibits an excellent yield and selectivity for ethylbenzene oxidation with O 2 /H 2 O by precise control of ˙OH formation.
Topics & Concepts
PolyoxometalateEthylbenzeneMetal-organic frameworkChemistryPhotochemistryRadicalMetalHydroxyl radicalInorganic chemistryOrganic chemistryCatalysisAdsorptionPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions