Quick-to-synthesize hybrid electrodes composed of activated carbon cloth with Co/Fe-based films as bifunctional electrocatalysts for water splitting
Izabela Walendzik, Karolina Kordek-Khalil, Piotr Rutkowski
Abstract
Hybrid electrodes have recently been investigated as attractive alternatives to noble-metal-based electrocatalysts for hydrogen production by water splitting. Herein, we propose an electrode composed of an oxidized carbon cloth with an electrodeposited bimetallic Co/Fe-based film. By optimizing the electrodeposition conditions and applying electrochemically activated carbon cloth as a substrate, one can prepare a free-standing noble-metal-free electrocatalytic electrode with high bifunctional electrocatalytic activity in hydrogen and oxygen evolution from alkaline solution. The developed Fe 0.25 Co 0.75 electrode requires overpotentials of 245 mV for HER and 360 mV for OER at high current densities of −100 and 100 mA cm −2 , respectively. Furthermore, its overall synthesis time from commercially available raw materials is only approximately 20 min. The electrode material was used as both a cathode and an anode in the model electrolyzer, which can deliver 10 mA cm −2 of current density at 1.66 V without loss of activity during 100 h of performance.