SnO <sub>2</sub> Nanoparticles: Green Synthesis, Characterization, and Water Treatment
A. S. Salwa, Azza El-Sayed Ahmed, H. S. Wasly, M. S. Abd El-Sadek
Abstract
The green synthesis approach was utilized to synthesize tin dioxide (SnO 2 ) nanoparticles (NPs) using Ocimum Basilicum leaves extract with different concentrations (10, 15, 20 ml) and different reaction temperatures (30, 60, 90 °C). The green synthesis method is considered economical, environmentally friendly, and non-toxic. X-ray diffraction patterns of the synthesized SnO 2 NPs have displayed a tetragonal crystalline structure. The crystallite size of SnO 2 NPs increased from 15.12 to 17.9 nm with increasing reaction temperature while decreasing from 20.68 to 17.9 nm with increasing extract concentrations. The morphology of the synthesized SnO 2 NPs was investigated using high-energy transmission electron microscopy (HR-TEM). The optical energy gap was determined using the diffuse reflectance UV–vis spectra range (300–1200) nm of SnO 2 NPs at different reaction temperatures and different extract concentrations. UV/Visible Spectrophotometer was used for studying the photodegradation of methylene blue dye (MB) dye. The photocatalytic degradation of MB revealed that SnO 2 NPs at reaction temperature 90 °C degraded 69% of MB solution when exposed to UV illumination for 90 min while the degradation reaches 90% for 180 min of exposure. It was obvious that the degradation rate of MB was increased with the increase of reaction temperature, and the extract concentration.