Modulating the microenvironment of AuPd nanoparticles using metal–organic frameworks for selective methane oxidation
Jianfei Sui, Ming‐Liang Gao, Chengyuan Liu, Yang Pan, Zheng Meng, Daqiang Yuan, Hai‐Long Jiang
Abstract
The AuPd nanoparticles incorporated into Cu 2+ -doped MOFs selectively oxidize CH 4 to CH 3 OH with H 2 O 2 as an oxidant. The Cu species can alter the CH 3 OH selectivity by modulating the AuPd electronic state to improve CH 4 adsorption and regulating the ˙OH formation.
Topics & Concepts
SelectivityMetal-organic frameworkNanoparticleMethaneAdsorptionChemistryMetalOxidation stateAnaerobic oxidation of methaneNanomaterialsInorganic chemistryChemical engineeringNanotechnologyMaterials scienceCatalysisOrganic chemistryEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions