Asymmetric assembly of pyrazole and 1,2,3-triazole with a methylene bridge: regioisomerism and energetic properties
Jin Xiong, Jinxiong Cai, Qi Lai, Ping Yin, Siping Pang
Abstract
An asymmetric N-bridged strategy was employed to link two different energetic building blocks. The resulting compounds not only exhibit good crystal density and low sensitivity, but also demonstrate the key features of physiochemical properties and regioisomeric structures that enrich the horizon of regiochemistry of energetic compounds.
Topics & Concepts
MethylenePyrazoleChemistryMethylene bridgeBridge (graph theory)TriazoleLink (geometry)Combinatorial chemistryStereochemistryOrganic chemistryMathematicsCombinatoricsInternal medicineMedicineEnergetic Materials and CombustionChemical Reaction MechanismsSynthesis of heterocyclic compounds