Reducing lifetime in Cu(<scp>i</scp>) complexes with thermally activated delayed fluorescence and phosphorescence promoted by chalcogenolate–diimine ligands
Giliandro Farias, Cristian A. M. Salla, Renata S. Heying, Adaı́lton J. Bortoluzzi, Sergio F. Curcio, Thiago Cazati, Paloma L. dos Santos, Andrew P. Monkman, Bernardo de Souza, Ivan H. Bechtold
Abstract
Cu(<sc>i</sc>) complexes without the expected heavy atom effect to enhance the spin–orbit coupling matrix elements, but with reduced photoluminescence lifetime.
Topics & Concepts
PhosphorescencePhotoluminescenceDiimineMaterials scienceFluorescenceAtom (system on chip)Spin–orbit interactionPhotochemistryCoupling (piping)OptoelectronicsChemistryCatalysisMetallurgyOrganic chemistryCondensed matter physicsPhysicsOpticsEmbedded systemComputer scienceOrganic Light-Emitting Diodes ResearchMagnetism in coordination complexesOrganometallic Complex Synthesis and Catalysis