Acylmonofluoromethylation of alkenes <i>via</i> dual NHC/photoredox catalysis
Shichao Tian, Mingxi Chen, Yihan Tang, Keguang Cheng, Gavin Chit Tsui, Quande Wang
Abstract
We herein describe a three-component radical acylmonofluoromethylation of alkenes by cooperative NHC/photoredox catalysis to synthesize various monofluorinated alkyl aryl ketones.
Topics & Concepts
ChemistryPhotoredox catalysisAlkylCatalysisArylDual (grammatical number)Dual roleCombinatorial chemistryComponent (thermodynamics)Organic chemistryPhotocatalysisThermodynamicsArtLiteraturePhysicsFluorine in Organic ChemistryRadical Photochemical Reactions