The Effect of Concentration of Lithium Salt on the Structural and Transport Properties of Ionic Liquid-Based Electrolytes
Jiahuan Tong, Shengli Wu, Nicolas von Solms, Xiaodong Liang, Feng Huo, Qing Zhou, Hongyan He, Suojiang Zhang
Abstract
Ionic liquids (ILs) are used as electrolytes in high-performance lithium-ion batteries, which can effectively improve battery safety and energy storage capacity. All atom molecular dynamics simulation and experiment were combined to investigate the effect of the concentration of lithium salt on the performance of electrolytes of four IL solvents ([Cnmim][TFSI] and [Cnmim][FSI], n=2,4). The IL electrolytes exhibit higher density and viscosity, meanwhile larger lithium ion transfer numbers as the concentration of LiTFSI increases. Furthermore, in order to explore the effect of the concentration of lithium salt on the ionic associations of Li+ and anion of IL, the microstructures of the lithium salt in various IL electrolytes at different concentrations were investigated. The structural analysis indicated strong bidentate and monodentate coordination were found between Li+ and anion of all IL electrolytes. Both cis and trans isomerism of [FSI]- were observed in [FSI]--type IL electrolytes systems. Furthermore, the existence of the ion cluster [Li[anion]x](x-1) - in IL electrolytes, and the cluster became more closed and compact as the concentration of LiTFSI increases.