Single-atom-nickel photocatalytic site-selective sulfonation of enamides to access amidosulfones
Jianjing Yang, Zongzhao Sun, Kelu Yan, Haozhe Dong, Hongyan Dong, Jiakai Cui, Xutao Gong, Shilin Han, Limin Huang, Jiangwei Wen
Abstract
A single-atom photocatalyst Ni/TiO<sub>2</sub> was developed for the visible-light-induced site-selective sulfonation of enamides to give amidosulfones with 36 examples up to 99% yield.
Topics & Concepts
NickelPhotocatalysisAtom (system on chip)ChemistryPhotochemistryCombinatorial chemistryCatalysisMaterials scienceOrganic chemistryComputer scienceEmbedded systemSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsAdvanced Photocatalysis Techniques