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Self-Powered Bipolar Photodetector Based on the MoO<sub><i>x</i></sub>/CdSe/SnTe Structure Toward the Application in Secure Optical Communication

Hailin Lei, Wei‐Hua Yan, Fan He, Min Zhang

2025ACS Applied Materials & Interfaces11 citationsDOI

Abstract

Bipolar photodetectors, characterized by their ability to reverse output current polarity in response to external illumination, have garnered significant research attention in recent years. This study presents a self-powered bipolar photodetector based on a MoO x /CdSe/SnTe heterostructure, emphasizing its potential application in secure optical communication systems. The device employs a back-to-back diode configuration, leveraging on the photovoltaic effect, to facilitate the separation and transportation of photogenerated charge carriers. The MoO x /CdSe and CdSe/SnTe junctions are instrumental in establishing the built-in potential, leading to the generation of a negative photocurrent under short-wavelength illumination and a positive photocurrent under long-wavelength illumination, exhibiting response times within the microsecond range. The device’s swift response and precise control make it highly suitable for secure communication systems. Employing the bipolar photodetector as a light signal receiver, a secure optical communication system was demonstrated, wherein the 735 nm light, serving as a positive valid signal, was effectively masked by the 405 nm light negative interference signal. This investigation provides valuable insights into the fabrication and performance optimization of wavelength-dependent bipolar photodetectors featuring a wide-narrow bandgap back-to-back diode heterostructure.

Topics & Concepts

PhotodetectorMaterials scienceOptoelectronics2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications
Self-Powered Bipolar Photodetector Based on the MoO<sub><i>x</i></sub>/CdSe/SnTe Structure Toward the Application in Secure Optical Communication | Litcius