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Combustion of <i>n</i>-C<sub>3</sub>–C<sub>6</sub> Linear Alcohols: An Experimental and Kinetic Modeling Study. Part I: Reaction Classes, Rate Rules, Model Lumping, and Validation

Matteo Pelucchi, Sylvain Namysl, E. Ranzi, Anne Rodriguez, Cristina Rizzo, Kieran P. Somers, Y. Zhang, Olivier Herbinet, Henry J. Curran, Frédérique Battin‐Leclerc, Tiziano Faravelli

2020Energy & Fuels36 citationsDOIOpen Access PDF

Abstract

= 704-935 K. These data are presented and discussed in detail in Part II, together with detailed comparisons with model predictions and a deep kinetic discussion. This work provides new experimental targets that are useful for kinetic model development and validation (Part II), as well as an extensively validated kinetic model (Part I), which also contains subsets of other reference components for real fuels, thus allowing the assessment of combustion properties of new sustainable fuels and fuel mixtures.

Topics & Concepts

Kinetic energyChemistryCombustionThermodynamicsAlcoholPyrolysisReaction rateReaction rate constantOrganic chemistryKineticsCatalysisPhysicsQuantum mechanicsAdvanced Combustion Engine TechnologiesCombustion and flame dynamicsHeat transfer and supercritical fluids
Combustion of <i>n</i>-C<sub>3</sub>–C<sub>6</sub> Linear Alcohols: An Experimental and Kinetic Modeling Study. Part I: Reaction Classes, Rate Rules, Model Lumping, and Validation | Litcius