The role of interactions between the cationic backbone and basic anions in green and ultra-selective catalytic synthesis of ethyl methyl carbonate in tunable ionized frameworks
Jie Chen, Jingjun Xie, Xiaoyan Chen, Rong Dong, Xue‐hui Ge, Ting Qiu
Abstract
The ionic framework [CPIL-M] n [PhO] with feasible Lewis basicity toward transesterification of dimethyl carbonate with ethanol for highly selective production of ethyl methyl carbonate (EMC) is reported.
Topics & Concepts
Cationic polymerizationCatalysisCarbonateChemistryIonizationQuantum chemicalIonOrganic chemistryMoleculeCarbon dioxide utilization in catalysisChemical Synthesis and Reactionsbiodegradable polymer synthesis and properties