Photocatalyzed Amidoarylation of 1,3‐Butadiene
Cyrille Gosset, Aurélien Moncomble, Clément Dumont, Sylvain Pellegrini, Till Bousquet, Mathieu Sauthier, Lydie Pélinski
Abstract
Abstract 1,3‐Butadiene is involved in a photocatalyzed amidoarylation reaction that allows the synthesis of N ‐allyl amides. The reaction was evaluated on a wide range of aryl diazonium salts and nitriles as co‐reactants. Selectivity issues were studied from the help of a computational approach. magnified image
Topics & Concepts
1,3-ButadieneArylSelectivityChemistryCombinatorial chemistryOrganic chemistryCatalysisAlkylRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods