Unveil the Triple Roles of Water Molecule on Power Generation of MXene Derived TiO<sub>2</sub> based Moisture Electric Generator
Chao Liu, Tao Wan, Peiyuan Guan, Mengyao Li, Shuo Zhang, Long Hu, Yu‐Chieh Kuo, Ziheng Feng, Fandi Chen, Yanzhe Zhu, Haowei Jia, Tao Cao, Tianyue Liang, Tushar Kumeria, Dawei Su, Dewei Chu
Abstract
Abstract Evaporation‐driven electricity generators have been proposed to generate electricity by water interacting with nanostructured materials. However, several proposed mechanisms, such as intrinsic gradient of polar functional groups principle and electrokinetic effect perspective, are in wide discrepancy. Here, through the combination of theoretical calculations involving time dimension on material's moisturizing process and experimental analyses, it is revealed the working principle through the water molecule triple roles in driving moisture electric generators (MEGs): 1) intrinsic H 2 O absorption on the material surface and splitting into hydroxy group and proton due to the polarizability of the material surface determined by the static electric potential of the materials. This process induces the electrochemical potential difference of the materials via the work function changes; 2) freely diffused protons derived from the H 2 O splitting work as the ions charge carriers; 3) via the hydrogen bond of the water molecules to drive charge carriers diffuse between opposite electrodes, maintaining the internal circuit current flow. It is successfully unveiled that anatase TiO 2 based materials for output voltage changes correlated to the domains’ work function's difference, tuning by the surface adsorption species (H, Cl, OH) and anisotropic exposed crystal facets of the material. This work unveils MEG's general working principle.