Bimetallic hexanuclear clusters in Ce/Zr-UiO-66 MOFs: <i>in situ</i> FTIR spectroscopy and modelling insights
Cesare Atzori, Kirill A. Lomachenko, Jannick Jacobsen, Norbert Stock, Alessandro Damin, Francesca Bonino, Silvia Bordiga
Abstract
groups allowed us to distinguish between two possible models: a solid solution or the presence of distinct clusters. This relatively straightfoward method should be also transferable to other mixed-metal metal-organic frameworks (MOFs).
Topics & Concepts
Bimetallic stripIn situFourier transform infrared spectroscopySpectroscopyMaterials scienceChemistryPhysical chemistryChemical engineeringCatalysisOrganic chemistryPhysicsQuantum mechanicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsInorganic Fluorides and Related CompoundsAdvanced Condensed Matter Physics