A perfect triangular dysprosium single-molecule magnet with virtually antiparallel Ising-like anisotropy
Guang Lü, Yang Liu, Wei Deng, Guo‐Zhang Huang, Yan‐Cong Chen, Jun‐Liang Liu, Zhao‐Ping Ni, Marcus J. Giansiracusa, Nicholas F. Chilton, Ming‐Liang Tong
Abstract
A perfect triangular Dy<sub>3</sub> single-molecule magnet was reported. Each Dy(<sc>iii</sc>) magnetic axis is oriented almost normal to the plane of Dy<sub>3</sub>, and the intramolecular magnetic dipole interaction gives rise to a virtually antiparallel Ising-like ground state.
Topics & Concepts
DysprosiumAntiparallel (mathematics)Single-molecule magnetIsing modelMagnetAnisotropyIntramolecular forceCondensed matter physicsMagnetic anisotropyDipoleGround stateCrystallographyMoleculePhysicsChemistryMagnetizationMagnetic fieldAtomic physicsQuantum mechanicsNuclear physicsMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes