Use of niobium oxide nanoparticles as nanofillers in <scp>PVP</scp> / <scp>PVA</scp> blends to enhance <scp>UV–visible</scp> absorption, opto‐linear, and nonlinear optical properties
H. Elhosiny Ali, M.A. Sayed, H. Algarni, Yasmin Khairy, M. Abdelaziz
Abstract
Abstract Transition metal oxide (TMO)—filled polymer films have numerous applications, including electromagnetic shielding and nonlinear optical devices. Nb 2 O 5 ‐filled polyvinyl pyrrolidone (PVP)/polyvinyl alcohol (PVA) blend was prepared using a solution casting process. Pristine and nanocomposite films from these blends were studied. X‐ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier infrared spectroscopy confirmed the formation of nanocomposites via interfacial interactions between the polymer chains and Nb 2 O 5 nanoparticles. These nanoparticles influence the amorphous nature and transparency of the PVA/PVP blends. The improvement of D opt (optical density) becomes particularly obvious in blended polymer films with considerable Nb 2 O 5 ‐nanofiller concentrations. By increasing the weight percentage of Nb 2 O 5 , the probability of producing additional levels in the bandgap increased. The optical absorption coefficient of each nanocomposite film was less than 10 6 m −1 , indicating indirect electron transfer. Thus, the indirect optical band‐gap declined from 3.9 to 1.9 eV as calculated from Tauc's and the absorption spectral fitting ( ASF ) formula. Additionally, the effects of Nb 2 O 5 on the extinction coefficient, refractive index, high‐frequency ( ε ∞ ), and static‐frequency ( ε o ) dielectrics have been reported. The nonlinear refractive index and optical susceptibilities ( x 1 and x 3 ) were enhanced by increasing the Nb 2 O 5 content in the blend. The penetration depth ( δ ) and optical limiting (OL) properties were also investigated. The developed nanocomposite materials could be used for advanced technology‐based devices such as reflective coatings, opto‐linear, and nonlinear optoelectronic applications.