Unraveling the mechanism and the role of hydrogen bonds in CO2 capture by diluent-free amine sorbents through a combination of experimental and theoretical methods
Gabriele Manca, Francesco Barzagli, Jakub Nagy, Markéta Munzarová, Maurizio Peruzzini, Andrea Ienco
Abstract
• Selected secondary amines efficiently capture CO2 without any additional diluent. • DPA shows dynamic CO2 absorption, forming carbamate/ammonium pairs at low loadings. • At higher CO2 loadings, carbamic acid becomes the predominant product. • Hydrogen bonds from free DPA stabilize carbamate, influencing product distribution. • NMR, FT-IR, and DFT analyses elucidate CO2 absorption mechanisms in DPA. The utilization of water-lean and non-aqueous amine sorbents is regarded as an appealing approach to reduce the energy costs of CO 2 capture via liquid sorbents. However, significant research is still needed to achieve the technological maturity required for industrial-scale implementation. Here, we present a detailed experimental and computational analysis at the molecular level of CO 2 capture by dipropylamine (DPA) as a case study to deepen our understanding of the mechanisms governing CO 2 absorption by liquid secondary amines that can be used without any additional diluent. CO 2 uptake with pure DPA was investigated, and the species produced over time were determined by NMR and FT-IR spectroscopy. In particular, the NMR analysis revealed the formation of carbamic acid at high CO 2 /DPA ratios. A detailed DFT investigation explained the mechanism of the reaction revealing a dynamic evolution in product distribution as CO 2 loading increases. At low CO 2 loadings, adducts with at least four DPA molecules are formed, ultimately leading to the carbamate/ammonium ionic pair stabilized through H-bonding interactions with DPA moieties. Conversely, at higher CO 2 levels some stabilizing DPA molecules of ionic pair are required for the CO 2 activation, resulting in the formation of carbamic acid. A reasonable mechanism for the evolution of product distribution is provided, and the main steps of the mechanistic picture are depicted and commented on. The dependence of carbamate and carbamic acid on the availability of hydrogen bond donors and acceptors in solution is also highlighted.