Intermolecular Hydroaminoalkylation of Propadiene
Tobias Kaper, Malte Fischer, Michael Warsitz, René Zimmering, Rüdiger Beckhaus, Sven Doye
Abstract
Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6-bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium-carbon bond of a titanaaziridine.
Topics & Concepts
Intermolecular forceCatalysisTitaniumChemistryCarbon fibersOrganic chemistryPolymer chemistryMaterials scienceMoleculeComposite materialComposite numberCatalytic C–H Functionalization MethodsAsymmetric Synthesis and CatalysisAsymmetric Hydrogenation and Catalysis