Disassembly Mechanisms and Energetics of Polymetallic Rings and Rotaxanes
Niklas Geue, Tom S. Bennett, Alexandra-Ana-Maria Arama, Lennart A. I. Ramakers, George F. S. Whitehead, Grigore A. Timco, P. B. Armentrout, Eric J. L. McInnes, Neil A. Burton, Richard E. P. Winpenny, Perdita E. Barran
Abstract
. Ion mobility probes the conformational landscape of the disassembly process from intact complex to structurally distinct isobaric fragments, providing unique insights to how a given divalent metal tunes the structural dynamics.
Topics & Concepts
ChemistryEnergeticsMechanism (biology)NanotechnologyComputational chemistryStereochemistryThermodynamicsPhysicsEpistemologyPhilosophyMaterials scienceSupramolecular Chemistry and ComplexesMass Spectrometry Techniques and ApplicationsCrystallography and molecular interactions