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Thermodynamic bounds for diffusion in nonequilibrium systems with multiple timescales

Andrea Plati, Andrea Puglisi, Alessandro Sarracino

2023Physical review. E15 citationsDOIOpen Access PDF

Abstract

We derive a thermodynamic uncertainty relation bounding the mean squared displacement of a Gaussian process with memory, driven out of equilibrium by unbalanced thermal baths and/or by external forces. Our bound is tighter with respect to previous results and also holds at finite time. We apply our findings to experimental and numerical data for a vibrofluidized granular medium, characterized by regimes of anomalous diffusion. In some cases our relation can distinguish between equilibrium and nonequilibrium behavior, a nontrivial inference task, particularly for Gaussian processes.

Topics & Concepts

Non-equilibrium thermodynamicsStatistical physicsBounding overwatchDiffusionPhysicsGaussianThermal equilibriumRelation (database)Gaussian processAnomalous diffusionThermodynamic processDiffusion processMean squared displacementDisplacement (psychology)ThermodynamicsComputer scienceMaterial propertiesQuantum mechanicsInnovation diffusionPsychologyMolecular dynamicsDatabaseArtificial intelligenceKnowledge managementPsychotherapistAdvanced Thermodynamics and Statistical MechanicsField-Flow Fractionation TechniquesStatistical Mechanics and Entropy
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