Multicomponent Reaction of Isocyanide, Ditelluride, and Mn(III) Carboxylate: Synthesis of <i>N</i>-Acyl Tellurocarbamate
Jianjian Zha, Zhuoer Wang, Bingxin Liu, Qitao Tan, Bin Xu
Abstract
A multicomponent reaction of isocyanides, ditellurides and manganese(III) carboxylates under mild reaction conditions leads to the synthesis of various N-acyl tellurocarbamates. This method demonstrates good functional tolerance and broad substrate scope and, as a result, is especially suitable for the postfunctionalization of complicated molecules such as drugs. The given method can be further extended to the synthesis of selenocarbamates.
Topics & Concepts
ChemistryIsocyanideCarboxylateManganeseSubstrate (aquarium)Combinatorial chemistryMoleculeScope (computer science)Reaction conditionsStereochemistryOrganic chemistryCatalysisComputer scienceGeologyOceanographyProgramming languageOrganoselenium and organotellurium chemistrySulfur-Based Synthesis TechniquesChemical Synthesis and Reactions