Work Function and Electron Affinity of Semiconductors: Doping Effect and Complication due to Fermi Level Pinning
Guosheng Shao
Abstract
Semiconductors are a major category of functional materials essential to various applications to sustain the modern society. Most applied materials or devices utilizing semiconductors are enabled by interfaces or junctions, such as solar cells, electronic/photonic devices, environmental sensors, and redox hetero‐catalysts. Herein, the author provides a critical commentary on photoemission measurement of the work function and, more importantly, the electron affinity of semiconductors essential for energy band diagram of heterojunctions. Particular effort is made towards addressing complications associated with Fermi level pinning due to surficial states of doped semiconductors.
Topics & Concepts
SemiconductorDopingWork functionHeterojunctionBand diagramFermi levelMaterials scienceCondensed matter physicsOptoelectronicsElectronNanotechnologyPhysicsQuantum mechanicsLayer (electronics)Electronic and Structural Properties of OxidesCopper-based nanomaterials and applicationsQuantum Dots Synthesis And Properties