μ-Oxo-bis[(octacosafluoro-<i>meso</i>-tetraphenylporphyrinato)iron(<scp>iii</scp>)] – synthesis, crystal structure, and catalytic activity in oxidation reactions
Tristan Schuh, Olga Kataeva, Hans‐Joachim Knölker
Abstract
We describe the synthesis and crystal structure of a novel perfluorinated μ-oxo-bis[(porphyrinato)iron( iii )] complex enabling useful applications in catalytic C–H activations including asymmetric biaryl coupling and Wacker-type oxidation of olefins.
Topics & Concepts
ChemistryCatalysisOxidative coupling of methaneMedicinal chemistryCrystal structureAlcoholKetoneOrganic chemistryCatalytic C–H Functionalization MethodsMetal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine Chemistry