Divergent reactivity of sulfinates with pyridinium salts based on one-<i>versus</i>two-electron pathways
Myojeong Kim, Euna You, Seongjin Park, Sungwoo Hong
Abstract
a three-component reaction, which provides facile access to a variety of β-pyridyl alkyl sulfones. These two reactions are orthogonal and complementary, achieving a broad substrate scope in a late-stage fashion under mild reaction conditions.
Topics & Concepts
PyridiniumReactivity (psychology)ChemistryCombinatorial chemistryComputational chemistryOrganic chemistryMedicinePathologyAlternative medicineSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions