Effect of hydrogen bonds and π⋯π interactions on the crystallization of phenyl-perfluorophenyl amides: understanding the self-organization of a cocrystal
Anderson B. Pagliari, Alexandre R. Meyer, Vanessa B. Solner, Jéssica M. L. Rosa, Manfredo Hörner, Hélio G. Bonacorso, Nilo Zanatta, Marcos A. P. Martins
Abstract
Crystallization mechanisms were proposed to investigate hydrogen bond and aromatic donor–acceptor interactions in a series of phenyl–perfluorophenyl amides. The modulation of NH⋯OC bonds and aryl complementarity drove a new cocrystal growth.
Topics & Concepts
CocrystalCrystallizationHydrogen bondArylAcceptorChemistryCrystallographyOrganic chemistryMoleculeAlkylCondensed matter physicsPhysicsCrystallography and molecular interactionsCrystallization and Solubility StudiesMolecular Spectroscopy and Structure